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| TP-pl-phosph |
Monitoring of a complete process line for the phosphatizing of metal surfaces using an at-line analysis system |
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| The ProcessLab analysis system controls, records and documents all the important analytical parameters of the entire phosphatizing process |
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| MI-2007-1-6 |
Using ProcessLab for monitoring a phosphatizing process |
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The metal surfaces are treated using strictly defined process steps in different degreasing, cleaning, rinsing, activation and phosphatizing baths. The various bath parameters have to be closely monitored as they determine to a large extend the
quality of the coating produced. The parameters determined in the cleaning, degreasing and rinsing baths are pH value, conductivity plus free and total alkalinity, while the phosphatizing bath is analyzed for free and total acids, nitrite or hydrogen peroxide, zinc and fluoride. The described ProcessLab at-line analysis system controls, records and documents the important analytical parameters of the entire phosphatizing process. The combination of the analytical methods involved as well as the intuitive handling via the well-arranged user interface allow for complete process control. The analytical functions are supplemented by the integrated operation software that offers numerous possibilities for data processing and documentation of the measured values. The at-line analysis system described meets all requirements regarding process monitoring and documentation. |
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| Article |
Metals in dip coating baths |
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| With an estimated worldwide turnover of more than 500 million Euros, phospatizing is the most important metal pretreatment process. ProcessLab is a customizable modular atline analysis system that records, controls and documents all important analytical bath parameters of the entire phosphatizing process. |
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| Article |
Routine process analysis – Compact analysis system for process environments |
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| In recent years analytical measuring has been transferred more and more from the laboratory to the plant. This places high demands on the analytical systems. They must be robust in order to function in the harsh process environment and optimally adapted to the particular process; they must also have interfaces for rapid internal and external communication via Ethernet, input/output lines, LIMS and databases. |
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| AN-V-168 |
Pb in phosphatation bath |
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| The concentration of Pb in a Zn phosphatation bath is determined by anodic stripping voltammetry (ASV) in HCl electrolyte. |
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| AN-V-167 |
Cd in phosphatation bath |
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| The concentration of Cd in a Zn phosphatation bath is determined by polarography in HCl electrolyte. |
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| AN-V-166 |
Ni in phosphatation bath |
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| The concentration of Ni in a Zn phosphatation bath is determined by polarography in ammonia buffer pH 9.3. |
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| AN-V-163 |
Fe in degreasing bath |
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| The concentration of Fe(total) is determined by polarography in an alkaline electrolyte containing triethanolamine (TEA) and KBrO3. All reagents typically contain iron impurities. Therefore a subtraction of the reagent blank is recommended. |
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| AN-V-104 |
Formaldehyde in metalworking lubricants |
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| Formaldehyde is determined polarographically at the DME in alkaline solution. |
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| AN-U-019 |
Chloride, nitrite, nitrate and sulfate in cooling lubricants (conductivity and UV detection) |
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| Determination of chloride, nitrite, nitrate and sulfate in cooling lubricants using anion chromatography with conductivity and UV detection after chemical suppression and inline sample preparation by dialysis. |
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| AN-S-191 |
Chloride, nitrite and sulfate in a used zinc bath containing cooling lubricants |
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| Determination of chloride, nitrite and sulfate in a used zinc bath using anion chromatography with conductivity detection after chemical suppression. |
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| AN-S-156 |
Chloride, nitrite, nitrate and sulfate in cooling lubricants (conductivity and UV detection) |
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| Determination of chloride, nitrite, nitrate and sulfate in cooling lubricants using anion chromatography with conductivity and UV detection (230 nm) after chemical suppression and inline sample preparation by dialysis. |
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| AN-H-064 |
Total base number (TBN) in oils |
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| Determination of Total Base Number (TBN) in new and used motor oils. |
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| AN-C-122 |
Cations including total iron content in antifreeze (monoethyleneglycol) |
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| Determination of sodium, potassium, iron(II), magnesium and calcium in antifreeze (monoethyleneglycol) using cation chromatography with direct conductivity detection. Ascorbic acid reduces iron(III) to iron(II). In this way total iron is determined as iron(II). |
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| AN-C-121 |
Strontium and barium in monoethyleneglycol |
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| Determination of strontium and barium in monoethyleneglycol using cation chromatography with direct conductivity detection. |
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| AB-310 |
Iodine adsorption number of carbon black according to ASTM D1510 |
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ProcessLab is a robust industrial analyzer that incorporates all needed equipment in a sealed case. It comes ready to use – including an industrial PC and operating unit as well as all needed analytical instruments. After the user has placed the sample(s) and pressed the start button, the system automatically carries out the calibration and sample determination(s). Detailed results are available for export via corporate ethernet or analog output lines.
The ProcessLab setup described here carries out a fully automated determination of the iodine adsorption number (IAN) of a carbon black using a sample processor.
That allows many samples to be analyzed in one single run. The setup includes the needed components for all measurements and, thanks to its flexibility, is able to meet specific demands on site. |
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| AB-292 |
Determination of nickel, hypophosphite and alkalinity in electroless nickel plating baths |
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Electroless nickel layers are normally nickel-phosphorus alloys. Sodium hypophosphite is used as the reducing agent (reductant) for the reductive chemical deposition of nickel with phosphorus inclusions.
To apply even nickel layers to the workpieces, the content of nickel, reductant and the alkalinity have to be determined periodically.
For the determination of the ingredients an automated ProcessLab system is used. All liquid handling steps such as taking sample aliquots, dosing reagents, titration and cleaning are performed by pumps and burets controlled by ProcessLab.
A sample aliquot is transferred either to the vessel for alkalinity and nickel analysis or to the vessel for reductant content determination. |
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| AB-289 |
Monitoring parameters in a phosphatizing process (pH, conductivity, acidity, alkalinity, fluoride and zinc) |
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The quality of a phosphatized metal surface depends directly on the composition of the phosphatizing baths. Because of the constant loss of bath reagents or contamination of the rinsing baths it is very important to constantly monitor these parameters. Keeping the consumption of phosphatizing agents as low as possible can optimize costs. In a modern factory you will find many different types of baths. It is very difficult to keep an eye on every single parameter. ProcessLab will monitor these by itself and, if desired, transmit the data to any suitable process control system (PCS). Alarm criteria can be set as well as external signals like a flashing alarm lamp. ProcessLab can, with the help of barcodes, automatically recognize the sample and the parameter which has to be analyzed. Place any sample on ProcessLab, register it and hit the “Start” button. All you get is the result at the desired place, e.g. as a report or a simple PDF file. Custom-designed for the particular needs of the process. The described ProcessLab at-line analysis system controls, records and documents the important analytical parameters of the entire phosphatizing process. The combination of the analytical methods involved as well as the intuitive handling via the well-arranged user interface allow complete process control. |
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| AB-220 |
Determination of ultratrace amounts of platinum by stripping voltammetry |
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| This Bulletin describes an analytical method for the determination of traces of Pt and Rh in the ppt range (ng/kg) by stripping voltammetry. Interest in the determination of even minute quantities of platinum and rhodium in environmental materials has greatly increased in recent years. Their emission into the environment from automobile exhaust gas catalytic converters is of great interest. The same applies to the determination of platinum in body fluids and tissue samples following chemotherapeutic treatment for cancer. Using the hanging mercury drop electrode (HMDE) and the DP (Differential Pulse) measuring technique, determination limits of approx. 0.1 ng/L Pt and 0.5 ng/L Rh can be achieved. |
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